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- W2052156944 abstract "The newly developed cation-exchange process was applied to convert Tl2Ba2Ca2Cu3O10 (Tl-2223) superconductors to HgBa2Ca2Cu3O8+δ (Hg-1223) superconductors via Tl–Hg cation-exchange in Hg-vapor at processing temperatures ranging from 700 to 800°C for 6–24 h. Oxygen annealing process at 350°C for 10 h was followed to optimize the content of oxygen in the Hg-1223 samples. The Tl-2223 phase has been successfully converted to Hg-1223 phase with a negligible amount of non-superconducting impurity phase. Tc values up to 135 K have been obtained in Hg-1223, which are ∼15 K higher than that of the original Tl-2223 compounds. Since the cation-exchange process is a kinetic process, it is very promising for fabrication of high-quality Hg-1223 superconductor at large scales." @default.
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- W2052156944 date "1999-09-01" @default.
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- W2052156944 title "Synthesis of Hg-1223 superconductors using a cation-exchange process" @default.
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- W2052156944 doi "https://doi.org/10.1016/s0921-4534(99)00414-1" @default.
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