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- W2052162610 abstract "1,2-Disilacyclohexanes are generally formed as products in the reaction of SiF 2 with alkenes. Unsymmetric methyl-substituted alkenes yield disilacyclohexanes with greater methyl substitution at C(2). Often two (or more isomeric) products are formed, and the reaction proceeds by a mechanism which allows isomerization of the methyl configurations. The disilacyclohexanes exist in distorted chair conformations and the chair-to-chair interconversion can be observed at low temperature in many cases. Consideration of the variable temperature 19 F spectra and the effect of methyl groups on average and individual 19 F chemical shifts allows assignment of configurations and preferred conformations of all disilacyclohexane derivatives." @default.
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- W2052162610 date "1980-03-01" @default.
- W2052162610 modified "2023-09-30" @default.
- W2052162610 title "A systematic investigation of the reaction of SiF2 with ethylene and six methyl-substituted ethylenes. III. Structures and conformational behaviour of 1,2-disilacyclohexane products" @default.
- W2052162610 doi "https://doi.org/10.1139/v80-069" @default.
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