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- W2052199879 abstract "We report the signature of an unconventional zwitterion in thick (>40 angstrom) L-cysteine films grown at low temperature (100 K) by means of sublimation in ultrahigh vacuum. Using X-ray photoelectron spectroscopy (XPS) we find that protonated amino groups (57%) are less prevalent than in films grown at higher temperatures. A large majority of the protonated amino groups receive the hydrogen through deprotonation of the thiol group (45%) and, in contrast, only a small fraction of the carboxylic groups (13%) is deprotonated. This shows, for the first time, the unconventional zwitterion to be the dominant species in L-cysteine. We believe the unusual growth parameters are responsible for this novel observation." @default.
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- W2052199879 date "2011-06-28" @default.
- W2052199879 modified "2023-09-23" @default.
- W2052199879 title "Unconventional Zwitterionic State of <scp>l</scp>-Cysteine" @default.
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- W2052199879 doi "https://doi.org/10.1021/jz2006918" @default.
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