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- W2052225964 abstract "Abstract Plots of logarithms of relative reaction rates of chromyl chloride oxidation and of chromic acid oxidation of alkenes (log k rel values) versus alkene ionization potentials (IPs) and versus their highest occupied molecular orbital energy levels (HOMOs) demonstrate excellent correlations. Each plot has a similar appearance and shows a single line with a positive slope. The results indicate that the rate‐determining step of each title reaction involves an electrophilic attack on the alkene π‐bond without significant steric effects; this supports a proposed 2 + 3 cycloaddition mechanism and disfavors a proposed stepwise 2 + 2 cycloaddition mechanism. Comparison is made with other d 0 transition metal complexes that oxidize alkenes. Copyright © 2004 John Wiley & Sons, Ltd." @default.
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- W2052225964 date "2004-08-13" @default.
- W2052225964 modified "2023-09-25" @default.
- W2052225964 title "Correlation of relative rates of chromyl chloride oxidation and chromic acid oxidation of acyclic alkenes versus alkene IPs and HOMOs" @default.
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- W2052225964 doi "https://doi.org/10.1002/poc.823" @default.
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