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- W2052247509 abstract "The soil bacterium Stenotrophomonas maltophilia was found to transform various long-chain fatty acids selectively into 3-hydroxy fatty acids of shorter chain length. Their chiral evaluation was performed by multidimensional gas chromatography (MDGC) on modified cyclodextrin phase comparing the enantiodistribution of 1,3-diol formed without loss of stereochemical information from a representative microbial product with those of synthetic (3RS)- and (3S)-1,3-diols. Enantiomeric excesses of 84–98% (R) were determined for the microbially produced 3-hydroxy acids. In addition, the CD exciton chirality method was applied to determine their absolute configuration. Derivatization with 9-anthryldiazomethane and 2-naphthoylimidazole led to the required bichromophoric structures. Their CD spectra displayed a positive first Cotton effect around 254 nm and a negative second Cotton effect around 237 nm, which confirmed the (R)-configuration of the bacterial products. Chirality 14:51–58, 2002. © 2002 Wiley-Liss, Inc." @default.
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- W2052247509 date "2001-12-11" @default.
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- W2052247509 title "Absolute configuration of 3-hydroxy acids formed byStenotrophomonas maltophilia: Application of multidimensional gas chromatography and circular dichroism spectroscopy" @default.
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- W2052247509 doi "https://doi.org/10.1002/chir.10029" @default.
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