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- W2052279085 abstract "Polyethylene glycol (PEG) glucosides (PEGG) and the PEGG esters of lauric acid were analyzed by atmospheric-pressure ionization MS (API-MS) with electrospray ionization. Straightforward mass characterization of the complex mixtures could be achieved without prior chromatographic separation. The constituents were identified on the basis of quasi-molecular ions. Individual components could be observed as protonated molecular ions [M+H]+ and/or as their NH4+, Na+, or K+ adducts in positive ion mode. The mass spectrometric investigation showed that mixtures of PEGG consisted of monoglucoside, diglucoside, polyglucoside, and free PEG. The esterification product is a mixture of two types of nonionic surfactants: PEG-laurates and PEGG-laurates. The reasons for distortion of the quasi-molecular ion intensities and the stabilization of adduct ions were discussed. The rapid and highly sensitive API-MS analysis technique proposed here is well suited for direct characterization of complex mixtures and suitable for development as a routine analytical method." @default.
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- W2052279085 date "2003-06-01" @default.
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- W2052279085 title "Analysis of the polyethylene glycol glucosides and FA esters thereof by atmospheric-pressure ionization MS" @default.
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- W2052279085 doi "https://doi.org/10.1007/s11746-003-0731-z" @default.
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