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• W2052397097 abstract "Abstract The electrochemical behaviour of lithium cells with a solid polymer electrolyte, P(EO) 8 ·LiClO 4 and a composite cathode with CuO as the active substance was studied at a temperature of 120 °C. The utilization of the CuO increases significantly with increasing content of acetylene black in pressed composite electrodes; the best results were obtained using 40 wt.% CuO+40 wt. C+20 wt.% P(EO) 8 ·LiClO 4 . The CuO composite cathode can be cycled in the potential range 1.5–3.0 V (versus Li/Li + ); the first cycle of the electrode yields about 135 mA h/g CuO but the capacity decreases rapidly in further cycles. The discharge of fresh Li/CuO cells occurs in two steps; however, a short heating period of unloaded cells leads to the conversion of CuO to a material that is discharged in a single step but with retention of the original coulombic capacity, which is close to the theoretical value of 674 mA h/g CuO. Because of the high initial potential of CuO (3.2 V versus Li/Li + ), the heating of fresh cells results in the degradation of the properties of the solid electrolyte, leading to rapid self-discharge of the cell. This can be avoided by decreasing the cathode potential to about 2.7 V either potentiostatically or by galvanostatic removal of charge corresponding to about 0.3% C t ." @default.
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• W2052397097 date "1991-10-01" @default.
• W2052397097 modified "2023-10-08" @default.
• W2052397097 title "A high-temperature lithiumcopper oxide cell with a solid polymer electrolyte" @default.
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• W2052397097 doi "https://doi.org/10.1016/0378-7753(91)80109-b" @default.
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