Matches in SemOpenAlex for { <https://semopenalex.org/work/W2052455748> ?p ?o ?g. }
- W2052455748 endingPage "190" @default.
- W2052455748 startingPage "185" @default.
- W2052455748 abstract "The radical cation of methylcyclohexane (Me-cC6) is detected by ESR after γ-irradiation at 77 K of a solid solution of the parent molecules in perfluoromethylcyclohexane (CF3-cC6F11) matrix. The isotropic 1H hyperfine (hf) splittings observed are identified with the help of a selectively deuteriated compound and INDO MO calculations: a1 = 20.1 G (2H), a2 = 42.7 G (2H), and a3 = 48.3 G (2H) for the two gauche protons of the methyl group, the equatorial methylene protons at the C2 and C6 positions, and those at the C3 and C5 positions, respectively, in a chair form with the methyl group at an equatorial position. The unpaired electron in Me-cC6+ occupies an a″ orbital in Cs symmetry. On warming, the radical cation undergoes deprotonation mainly at either the C3 (or C5) or C4 or both." @default.
- W2052455748 created "2016-06-24" @default.
- W2052455748 creator A5046753098 @default.
- W2052455748 creator A5058563780 @default.
- W2052455748 creator A5060207652 @default.
- W2052455748 date "1988-08-01" @default.
- W2052455748 modified "2023-09-25" @default.
- W2052455748 title "Structure and reaction of methylcyclohexane radical cation: ESR studies" @default.
- W2052455748 cites W1972526584 @default.
- W2052455748 cites W1980835312 @default.
- W2052455748 cites W1990276081 @default.
- W2052455748 cites W1997045715 @default.
- W2052455748 cites W1999449343 @default.
- W2052455748 cites W2007278080 @default.
- W2052455748 cites W2008448438 @default.
- W2052455748 cites W2009949000 @default.
- W2052455748 cites W2018563956 @default.
- W2052455748 cites W2020849761 @default.
- W2052455748 cites W2021331367 @default.
- W2052455748 cites W2023677845 @default.
- W2052455748 cites W2040593102 @default.
- W2052455748 cites W2079955895 @default.
- W2052455748 cites W2082943804 @default.
- W2052455748 cites W2095318624 @default.
- W2052455748 cites W2112477340 @default.
- W2052455748 cites W2146406469 @default.
- W2052455748 cites W2344734424 @default.
- W2052455748 cites W2622425062 @default.
- W2052455748 cites W2949992820 @default.
- W2052455748 doi "https://doi.org/10.1016/0009-2614(88)87219-1" @default.
- W2052455748 hasPublicationYear "1988" @default.
- W2052455748 type Work @default.
- W2052455748 sameAs 2052455748 @default.
- W2052455748 citedByCount "24" @default.
- W2052455748 countsByYear W20524557482012 @default.
- W2052455748 countsByYear W20524557482021 @default.
- W2052455748 crossrefType "journal-article" @default.
- W2052455748 hasAuthorship W2052455748A5046753098 @default.
- W2052455748 hasAuthorship W2052455748A5058563780 @default.
- W2052455748 hasAuthorship W2052455748A5060207652 @default.
- W2052455748 hasConcept C118629725 @default.
- W2052455748 hasConcept C121332964 @default.
- W2052455748 hasConcept C131538251 @default.
- W2052455748 hasConcept C139066938 @default.
- W2052455748 hasConcept C145148216 @default.
- W2052455748 hasConcept C155647269 @default.
- W2052455748 hasConcept C161790260 @default.
- W2052455748 hasConcept C178790620 @default.
- W2052455748 hasConcept C184779094 @default.
- W2052455748 hasConcept C185592680 @default.
- W2052455748 hasConcept C186927785 @default.
- W2052455748 hasConcept C187961010 @default.
- W2052455748 hasConcept C2776504022 @default.
- W2052455748 hasConcept C2777454769 @default.
- W2052455748 hasConcept C2778565081 @default.
- W2052455748 hasConcept C2781311116 @default.
- W2052455748 hasConcept C32909587 @default.
- W2052455748 hasConcept C46141821 @default.
- W2052455748 hasConcept C75473681 @default.
- W2052455748 hasConcept C8010536 @default.
- W2052455748 hasConcept C96444392 @default.
- W2052455748 hasConceptScore W2052455748C118629725 @default.
- W2052455748 hasConceptScore W2052455748C121332964 @default.
- W2052455748 hasConceptScore W2052455748C131538251 @default.
- W2052455748 hasConceptScore W2052455748C139066938 @default.
- W2052455748 hasConceptScore W2052455748C145148216 @default.
- W2052455748 hasConceptScore W2052455748C155647269 @default.
- W2052455748 hasConceptScore W2052455748C161790260 @default.
- W2052455748 hasConceptScore W2052455748C178790620 @default.
- W2052455748 hasConceptScore W2052455748C184779094 @default.
- W2052455748 hasConceptScore W2052455748C185592680 @default.
- W2052455748 hasConceptScore W2052455748C186927785 @default.
- W2052455748 hasConceptScore W2052455748C187961010 @default.
- W2052455748 hasConceptScore W2052455748C2776504022 @default.
- W2052455748 hasConceptScore W2052455748C2777454769 @default.
- W2052455748 hasConceptScore W2052455748C2778565081 @default.
- W2052455748 hasConceptScore W2052455748C2781311116 @default.
- W2052455748 hasConceptScore W2052455748C32909587 @default.
- W2052455748 hasConceptScore W2052455748C46141821 @default.
- W2052455748 hasConceptScore W2052455748C75473681 @default.
- W2052455748 hasConceptScore W2052455748C8010536 @default.
- W2052455748 hasConceptScore W2052455748C96444392 @default.
- W2052455748 hasIssue "2" @default.
- W2052455748 hasLocation W20524557481 @default.
- W2052455748 hasOpenAccess W2052455748 @default.
- W2052455748 hasPrimaryLocation W20524557481 @default.
- W2052455748 hasRelatedWork W1964015015 @default.
- W2052455748 hasRelatedWork W1969936130 @default.
- W2052455748 hasRelatedWork W1996394995 @default.
- W2052455748 hasRelatedWork W2035454390 @default.
- W2052455748 hasRelatedWork W2052455748 @default.
- W2052455748 hasRelatedWork W2061688055 @default.
- W2052455748 hasRelatedWork W2155659872 @default.
- W2052455748 hasRelatedWork W2537233966 @default.
- W2052455748 hasRelatedWork W3104261492 @default.
- W2052455748 hasRelatedWork W2019771708 @default.
- W2052455748 hasVolume "149" @default.
- W2052455748 isParatext "false" @default.