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- W2052460127 abstract "In the current work, we investigated the Thermogravimetric kinetics of degradation of high-density polyethylene (HDPE) alone, and mixed with silicoaluminophosphate catalyst (SAPO-37/HDPE). To estimate the kinetic parameters of the polymer degradation, the Vyazovkin model-free kinetic method was applied. The activation energy (E) was calculated as a function of conversion (α) and temperature (T), providing an estimate of the time required for the degradation process at a given temperature. The products due to thermal and catalytic cracking of polyethylene were analyzed by gas chromatography/mass spectrometry (GC/MS). The SAPO-37 showed good catalytic activity, decreasing the activation energy for the process." @default.
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- W2052460127 date "2002-09-01" @default.
- W2052460127 modified "2023-09-26" @default.
- W2052460127 title "Thermogravimetric kinetics of polyethelyne degredation over silicoaluminophosphate" @default.
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- W2052460127 doi "https://doi.org/10.1016/s0040-6031(02)00072-2" @default.
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