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• W2052474853 abstract "The geometrical structures and relative stability of the various possible isomers of silicon–oxygen–sulfur oligomers, (SiOS)n (n = 1–6), were studied using quantum chemistry calculations. The linear monomer with Si atom bonding to both O and S atoms is the ground state isomer, and the rhombic chains of four-membered rings are the most stable configurations for n = 2–4, while the hybrid structures by the 4MRs and hexagonal six-membered ring become energetically most favorable for n = 5 and n = 6. Vibrational frequency calculations show that the characteristic IR signatures occur at 1290 cm−1 for n = 1, at the vicinity of 900 cm−1 for n = 2–4, and at about 1080 cm−1 for n = 5–6. These distinctive spectra would provide guide for future experimental detections of these small Si–O–S oligomers." @default.
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• W2052474853 date "2005-03-01" @default.
• W2052474853 modified "2023-09-26" @default.
• W2052474853 title "Theoretical study of silicon–oxygen–sulfur oligomers (SiOS)n (n=1–6)" @default.
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• W2052474853 doi "https://doi.org/10.1016/j.cplett.2005.01.082" @default.
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