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- W2052490717 abstract "Abstract A number of mixed ligand complexes of the type [Co(en) 2 (Im)Cl]Cl 2 (Im = imidazole or a substituted imidazole) have been synthesized by reaction of trans -[Co(en 2 Cl 2 ]Cl with the imidazole ligands. Electrical conductivity measurements support the ionic (1:2) formulation of the compounds, the electronic spectra is in agreement with an octahedral stereochemistry, and the IR and NMR ( 1 H and 13 C) spectra strongly favour the cis configuration for the isolated complexes, [Co(en) 2 (Im)Cl]Cl 2 . Trans -[Co(en) 2 Cl 2 ]Cl reacts with KNCS to form cis -[Co(en) 2 (NCS) 2 Cl, the crystal structure of which is briefly reported. This lends additional support in favour of the probable cis configuration of the above complexes." @default.
- W2052490717 created "2016-06-24" @default.
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- W2052490717 date "1981-03-01" @default.
- W2052490717 modified "2023-09-27" @default.
- W2052490717 title "1H and 13C NRM and infrared spectral studies on mixed ligand complexes of the type cis-[Co(en)2(Im)Cl]Cl2" @default.
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- W2052490717 doi "https://doi.org/10.1016/0022-2860(81)85028-4" @default.
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