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• W2052495424 abstract "The interaction of the following nitrogensulphur donor ligands with copper has been investigated: 2-(3,3-dimethyl-2-thiabutyl)benzimidazole (L1), 2-(3,3-dimethyl-2-thiabutyl)quinoline (L2), 2-ethylthioethylamine (L3), 2-(2-thiabutyl)pyridine (L4), 2-(2-pentafluorophenyl-2-thiaethyl)pyridine (L5), 2-methylthio-2-imidazoline (L6), and 2-methylthiobenzimidazole (L7). The copper(II) complexes CuLX2 (L = L1, L2, L3 or L4, X = Cl or Br), CuL2X2·H20 (L = L1, X = ClO4; L = L7, X = BF4), CuL2X2 (L = L3, L5 or L7, X = Cl or Br; L = L3 or L4, X = BF4; L = L3, X = ClO4; L = L7, X = NO3), [CuL2X]BF4 (L = L3, X = Cl; L = L4, X = Br), CuL32(SO4), CuL64 X2 (X = Cl, Br or BF4) and the copper(I) complexes CuL2Br, Cu(L2H)Br2 and CuL22(ClO4) have been isolated and structures proposed on the basis of conductivity, infrared, electronic and e.s.r. spectral measurements. The study shows that the use of sterically bulky thioether ligands can induce Cu(II) to adopt a pseudo-tetrahedral coordination as in the complexes CuLX2 (L = L1 or L2, X = Cl or Br). In the ligands L5, L6 and L7, the thioether sulphur does not coordinate strongly to Cu(II) if at all. E.s.r. data indicate that the Cu(II) complexes undergo extensive solvation and dissociation in methanol." @default.
• W2052495424 created "2016-06-24" @default.
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• W2052495424 date "1982-01-01" @default.
• W2052495424 modified "2023-09-26" @default.
• W2052495424 title "Sulphur ligand metal complexes. Part 15. [1]. Sulphurnitrogen donor ligand complexes of copper" @default.
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• W2052495424 doi "https://doi.org/10.1016/s0020-1693(00)91146-0" @default.
• W2052495424 hasPublicationYear "1982" @default.
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