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- W2052505989 abstract "On the basis of the Kramers–Henneberger (KH) high-frequency approximation, we carried out an ab initio molecular orbital calculation for He2 in intense laser fields. The potential energy curve is found to be attractive, indicating that a He–He chemical bond is formed. The formation of the He–He chemical bond is ascribable to changes in the nature of KH molecular orbitals. Intense laser fields cause a kind of sp hybridization of KH atomic orbitals. The degree of the hybridization depends on the internuclear distance, and reaches a maximum at around the equilibrium internuclear distance. This hybridization remarkably strengthens/weakens the bonding/anti-bonding character of the 1σg/1σu KH molecular orbitals, respectively." @default.
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- W2052505989 date "2004-07-21" @default.
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- W2052505989 title "He–He chemical bonding in high-frequency intense laser fields" @default.
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- W2052505989 doi "https://doi.org/10.1088/0953-4075/37/15/010" @default.
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