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• W2052512352 abstract "Three Fluorines at Once The trifluoromethyl (CF 3 ) group is playing an increasingly important role in the design of pharmaceutical and agrochemical compounds. CF 3 is a powerful attractor of electron density within a given molecular framework, and recently fluorine-hydrocarbon interactions have emerged as a distinct complement to the more traditional hydrophilic/hydrophobic interplay that governs docking between small molecules and proteins. Cho et al. (p. 1679 ) now present an efficient method for appending CF 3 groups to a broad range of aryl substrates. A carefully optimized palladium catalyst was able to speed up a critical elimination step that has plagued previous efforts to realize a general solution to this synthetic challenge." @default.
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• W2052512352 date "2010-06-25" @default.
• W2052512352 modified "2023-10-02" @default.
• W2052512352 title "The Palladium-Catalyzed Trifluoromethylation of Aryl Chlorides" @default.
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• W2052512352 doi "https://doi.org/10.1126/science.1190524" @default.
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