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- W2052516941 abstract "Polyaddition reactions in miniemulsions were successfully performed by miniemulsification of mixtures of di-, tri-, and tetra-epoxides with varying diamines, dithiols, or bisphenols, and subsequent heating to 60°C. This expands the potential applications of the family of miniemulsification techniques to generate aqueous polymer dispersions, since miniemulsions were previously just employed for the radical polymerization of vinylic monomers. Depending on the chemical nature of the monomers, the amount of surfactant, and the pH of the reaction mixture, latex particles with diameters between 30 and 600 nm and sometimes very narrow particle size distributions were obtained. Gel permeation chromatography (GPC) measurements on the final polyaddition products reveal molecular weights of about 20 000 with a polydispersity index of close to 2, i. e., close to ideal reaction conditions are preserved throughout the heterophase reaction." @default.
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- W2052516941 date "2000-01-01" @default.
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- W2052516941 title "Polyaddition in miniemulsions: A new route to polymer dispersions" @default.
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- W2052516941 doi "https://doi.org/10.1002/(sici)1521-3935(20000101)201:1<1::aid-macp1>3.0.co;2-n" @default.
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