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- W2052538000 abstract "Carbon−carbon bond activation by subsurface hydrogen has been observed for adsorbed cyclopropane at 170 K on the Ni(111) surface. Propane was the dominant product, and no multiple C−C bond activation processes were observed. Cyclopropane desorbs at 124 K from both the clean and the hydrogen-coadsorbed Ni(111) surface. Neither coadsorbed hydrogen nor disproportionation induces propane formation. These observations are consistent with previous results that energetic forms of hydrogen are necessary to activate the C−C bond even in strained cyclopropane under ultrahigh-vacuum conditions." @default.
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- W2052538000 date "1998-01-22" @default.
- W2052538000 modified "2023-09-28" @default.
- W2052538000 title "Carbon−Carbon Bond Activation of Cyclopropane by Subsurface Hydrogen on the Ni(111) Surface" @default.
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- W2052538000 doi "https://doi.org/10.1021/la970720s" @default.
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