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- W2052584476 abstract "Abstract The conformation of chiral 2,2′-dinitro-3,3′-bithienyl-4,4′-dicarboxylic acid ( Ia ), its dimethylester ( Ib ), and analogous selenium derivatives Ic and Id was investigated by means of induced cholesteric mesophases. A parallel investigation on the diester ( Ib ) and on other model 3,3′-bithienyls was carried out with dipole moment measurements. The conclusions reached with the two independent methods for derivative Ib are in excellent agreement and indicate, if a single conformation is assumed, a preferred cisoid conformation with a dihedral angle somewhat smaller than 90°. Alternatively, if the existence of both cisoid and transoid conformations having supplementary dihedral angles is assumed, the data indicate a higher population for the cisoid form." @default.
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- W2052584476 date "1986-10-01" @default.
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- W2052584476 title "A study of the conformation of some 3,3′-bithienyl and biselenienyl derivatives by measurements of twisting powers in nematic liquid crystals and of dipole moments" @default.
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