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- W2052594118 abstract "The preparation and characterization of the substituted bis(cyclopentadienyl) zirconium dichloride complexes (η5-C5H4CMe2C9H7)2ZrCl2 (1a, b) is reported. The isomer mixture of 1a, b was treated with different reducing agents such as sodium and n-butyllithium under various reaction conditions. In these reactions CC and CH activation and cleavage reactions were observed. In combination with methylaluminoxane (MAO) 1a, b and 3 showed low activities as homogeneous ethylene polymerization catalysts and no activities towards propylene. Compounds 2 and 3 were characterized by NMR spectroscopy and X-ray crystallography." @default.
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- W2052594118 date "1998-06-01" @default.
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- W2052594118 title "Reduction reactions of the metallocene complex (η5-C5H4CMe2C9H7)2ZrCl2" @default.
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- W2052594118 doi "https://doi.org/10.1016/s0022-328x(98)00477-x" @default.
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