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• W2052597958 abstract "Abstract The single crystals of the NaClO 4 complexes with two potential lariat 15-crowns-5 having ortho - or para -methoxyphenoxymethyl side arms were investigated by X-ray analysis in racemic and enantiopure form. Only ortho -derivative demonstrates lariat effect, i.e. the assistance of lateral fragment in cation complexation. No one oxygen atom of para -substituted side arm takes part in guest encapsulation in the solid phase. Whereas the crystals of racemic and enantiopure ortho -substituted crown complexes differ substantially from one another in packing characteristics, racemic and enantiopure complexes of para -derivatives are almost isostructural. This fact indicates that the last chiral complex belong to the rare class of continuous solid solutions of enantiomers." @default.
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• W2052597958 date "2013-01-01" @default.
• W2052597958 modified "2023-09-26" @default.
• W2052597958 title "Crystallographic evidence of side-arm lariat effect in the series of chiral ortho- and para-methoxyphenoxymethyl-15-crown-5 complexes with sodium perchlorate" @default.
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• W2052597958 doi "https://doi.org/10.1016/j.molstruc.2012.07.053" @default.
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