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- W2052614663 abstract "Abstract Recently we found that some chiral compounds possessing molecular biaxiality can stabilize an amorphous blue phase III. We introduced a polar group into the chiral T-shaped molecule in order to couple the molecule with an electric field. We prepared some novel T-shaped chiral compounds possessing a 4-cyanobiphenyl moiety and a mesogenic unit with a chiral center. We investigated their phase transition temperatures and induced helical pitches. We discuss structure-property correlations of the newly designed T-shaped chiral oligomers. Keywords: Liquid crystalschiralityblue phasehelical pitch Acknowledgments This work was partially supported by Research for Promoting Technological Seeds, JST, and a Grant-in-Aid for Scientific Research from Japan Society for the Promotion of Science (No. 19550175). Notes a Compounds I and III exhibited N * to glass transitions on cooling at −10°C and 9°C, respectively. b The cooling rate was 0.1°Cmin− 1 from the isotropic phase to appearance of the blue phase." @default.
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- W2052614663 date "2008-05-21" @default.
- W2052614663 modified "2023-10-16" @default.
- W2052614663 title "Synthesis and Physical Properties of Novel T-Shaped Chiral Liquid Crystal Oligomers Possessing Terminal Cyano Groups" @default.
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- W2052614663 doi "https://doi.org/10.1080/00150190802046596" @default.
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