Matches in SemOpenAlex for { <https://semopenalex.org/work/W2052622752> ?p ?o ?g. }
- W2052622752 endingPage "63" @default.
- W2052622752 startingPage "55" @default.
- W2052622752 abstract "The dynamics of charge recombination (CR) reactions after photoinduced charge separation (CS) in self-assembled ion pairs of charged porphyrins and oppositely charged electron acceptors were studied in aqueous solution. In most cases the CS reaction occurs in times less than 0.1 ps after the photoexcitation event, whereas the CR reaction is slower, on the multipicosecond time scale. The CR reactions show an invariance of rate constant (ca. 1012 s−1) with driving force at Δ G ⪅ 1.2 eV. Moreover, the CR processes exhibited a strongly inverted dependence on driving force when Δ G > 1.3 eV. The rate constants of CR reactions in the region independent of driving force were insensitive to changes in the longitudinal relaxation time of the solvent, as determined by changing the solvent from neat water to alcohol-water mixtures, which may indicate that the CR reaction rate in the driving force independent region is limited by vibrational relaxation in the ground state of the complex." @default.
- W2052622752 created "2016-06-24" @default.
- W2052622752 creator A5009626835 @default.
- W2052622752 creator A5045804863 @default.
- W2052622752 date "1997-05-01" @default.
- W2052622752 modified "2023-09-27" @default.
- W2052622752 title "Charge recombination reactions in self-assembled porphyrin-based ion-pair complexes" @default.
- W2052622752 cites W1964757697 @default.
- W2052622752 cites W1966682263 @default.
- W2052622752 cites W1967928815 @default.
- W2052622752 cites W1968067159 @default.
- W2052622752 cites W1969756314 @default.
- W2052622752 cites W1973709609 @default.
- W2052622752 cites W1974786218 @default.
- W2052622752 cites W1982572263 @default.
- W2052622752 cites W1985889445 @default.
- W2052622752 cites W1989960605 @default.
- W2052622752 cites W1991110952 @default.
- W2052622752 cites W2000124719 @default.
- W2052622752 cites W2006042845 @default.
- W2052622752 cites W2010350248 @default.
- W2052622752 cites W2010802041 @default.
- W2052622752 cites W2011818093 @default.
- W2052622752 cites W2016090732 @default.
- W2052622752 cites W2016605274 @default.
- W2052622752 cites W2017241584 @default.
- W2052622752 cites W2020664548 @default.
- W2052622752 cites W2020985880 @default.
- W2052622752 cites W2024067522 @default.
- W2052622752 cites W2025864708 @default.
- W2052622752 cites W2031904472 @default.
- W2052622752 cites W2032545752 @default.
- W2052622752 cites W2032774090 @default.
- W2052622752 cites W2041294529 @default.
- W2052622752 cites W2044942114 @default.
- W2052622752 cites W2049768819 @default.
- W2052622752 cites W2052908097 @default.
- W2052622752 cites W2053437896 @default.
- W2052622752 cites W2053804572 @default.
- W2052622752 cites W2064792793 @default.
- W2052622752 cites W2067284685 @default.
- W2052622752 cites W2069425097 @default.
- W2052622752 cites W2070462051 @default.
- W2052622752 cites W2071084287 @default.
- W2052622752 cites W2071703333 @default.
- W2052622752 cites W2074608219 @default.
- W2052622752 cites W2078995652 @default.
- W2052622752 cites W2083299124 @default.
- W2052622752 cites W2084933693 @default.
- W2052622752 cites W2086155660 @default.
- W2052622752 cites W2088344295 @default.
- W2052622752 cites W2091985234 @default.
- W2052622752 cites W2096927321 @default.
- W2052622752 cites W2104166397 @default.
- W2052622752 cites W2119549363 @default.
- W2052622752 cites W2126191236 @default.
- W2052622752 cites W2134888823 @default.
- W2052622752 cites W260588222 @default.
- W2052622752 cites W2949676789 @default.
- W2052622752 cites W2952434720 @default.
- W2052622752 cites W3004685355 @default.
- W2052622752 doi "https://doi.org/10.1016/s1010-6030(96)04468-1" @default.
- W2052622752 hasPublicationYear "1997" @default.
- W2052622752 type Work @default.
- W2052622752 sameAs 2052622752 @default.
- W2052622752 citedByCount "7" @default.
- W2052622752 countsByYear W20526227522022 @default.
- W2052622752 crossrefType "journal-article" @default.
- W2052622752 hasAuthorship W2052622752A5009626835 @default.
- W2052622752 hasAuthorship W2052622752A5045804863 @default.
- W2052622752 hasConcept C104317684 @default.
- W2052622752 hasConcept C121332964 @default.
- W2052622752 hasConcept C145148216 @default.
- W2052622752 hasConcept C147789679 @default.
- W2052622752 hasConcept C148898269 @default.
- W2052622752 hasConcept C155220765 @default.
- W2052622752 hasConcept C156695909 @default.
- W2052622752 hasConcept C15744967 @default.
- W2052622752 hasConcept C159467904 @default.
- W2052622752 hasConcept C178790620 @default.
- W2052622752 hasConcept C181500209 @default.
- W2052622752 hasConcept C184651966 @default.
- W2052622752 hasConcept C184779094 @default.
- W2052622752 hasConcept C185592680 @default.
- W2052622752 hasConcept C2776029896 @default.
- W2052622752 hasConcept C2779480358 @default.
- W2052622752 hasConcept C2780471494 @default.
- W2052622752 hasConcept C55493867 @default.
- W2052622752 hasConcept C62520636 @default.
- W2052622752 hasConcept C75473681 @default.
- W2052622752 hasConcept C77805123 @default.
- W2052622752 hasConcept C93391505 @default.
- W2052622752 hasConceptScore W2052622752C104317684 @default.
- W2052622752 hasConceptScore W2052622752C121332964 @default.
- W2052622752 hasConceptScore W2052622752C145148216 @default.
- W2052622752 hasConceptScore W2052622752C147789679 @default.
- W2052622752 hasConceptScore W2052622752C148898269 @default.
- W2052622752 hasConceptScore W2052622752C155220765 @default.