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- W2052662337 abstract "The monitoring by UV spectroscopy of the Pd-catalyzed hydrogenolysis in acetonitrile of 2-methyl-2-benzyloxycarbonyl-1-indanone and 2-methyl-2-benzyloxycarbonyl-1-tetralone showed the successive formation of corresponding beta-ketoacids and enols to deliver finally the ketones. Some factors which influence the stability of the intermediates are determined. In contrast to the above benzyl beta-ketoesters, the enol was not detected from benzyl (2-methylinden-3-yl) carbonate." @default.
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- W2052662337 date "2004-09-04" @default.
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- W2052662337 title "Mechanistic Insights into the Palladium-Induced Domino Reaction Leading to Ketones from Benzyl β-Ketoesters: First Characterization of the Enol as an Intermediate" @default.
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- W2052662337 doi "https://doi.org/10.1021/jo049464w" @default.
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