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- W2052711627 abstract "Abstract Thermal analysis studies coupled with chemical studies indicate that glycopyranosides undergo thermal decomposition in two overlapping stages. The initial reaction of the glycosides at temperature between 200 and 300°C is cleavage and volatilization of the glycosidic group as the corresponding alcohol, followed by intra- or inter-molecular condensation of the glycosyl portion of the molecule. At higher temperatures (310–340°C) the major reaction is fragmentation of the carbohydrate into a variety of low molecular-weight compounds. Studies with a series of anomeric methyl and phenyl glycosides indicate that, with the methyl and phenyl glycosides, the rate of the low-temperature condensation reaction was dependent on anomeric configuration of the starting glycoside." @default.
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- W2052711627 date "1984-08-01" @default.
- W2052711627 modified "2023-09-27" @default.
- W2052711627 title "Thermal decomposition of anomeric glycopyranosides" @default.
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- W2052711627 doi "https://doi.org/10.1016/0165-2370(84)80025-x" @default.
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