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- W2052744277 abstract "Aus 1.3.4.6-Tetraacetyl-N-benzoyl-D-glucosamin wird α-1-Chlor-3.4.6-triacetyl-N-benzoyl-D-glucosamin (I) erhalten, das in normaler Weise in Glykoside des D-Glucosamins übergeführt und in α-1-Benzoyl-3.4.6-triacetyl-D-glucoamin-hydrochlorid (II) umgelagert werden kann. β-Glucosaminide werden ferner nach der Oxazolin-Methode dargestellt. Ausgehend vom 2-Phenyl-4.5-[3.4.6-triacetyl-D-glucopyrano]-Δ2-oxazolin (IV) und seinem Hydrobromid (III) werden β-N-Glykoside und β-O-Glykosidderivate des D-Glucosamins, insbesondere mit D-Serin und L-Serin gewonnen. Die Oxazolinbase (IV) läßt sich in 2-Phenyl-4.5-[D-glucopyrano]-Δ2-oxazolin (VII) überführen, aus dem β-1-Acetyl-N-benzoyl-D-glucosamin (VIII) dargestellt wird. Es werden ferner β-N-Glucosaminide gewonnen (IX, X, XI)." @default.
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- W2052744277 date "1960-10-01" @default.
- W2052744277 modified "2023-10-16" @default.
- W2052744277 title "Über die Reaktionen des <scp>D</scp> ‐Glucosamins, XIV. Darstellung von Glykosiden des <scp>D</scp> ‐Glucosamins" @default.
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- W2052744277 doi "https://doi.org/10.1002/cber.19600931032" @default.
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