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- W2052783457 abstract "Pyrolysis of H3Os3(CO)9(μ3-CC6H5) (1) in a sealed glass tube at 220°C gives the known methylbenzyne complex H2Os3(CO)9(μ3,η 2-C6H3CH3) (2), previously prepared from Os3(CO)10(NCCH3)2 and toluene. Similar pyrolysis (220°C) of 2 either as a solid or in tridecane solution shows significant conversion to 1, demonstrating reversibility. Pyrolysis of H3Os3(CO)9(μ3-CC6D5) (1-d5) provides 2, which shows scrambling of the deuterium atoms into all sites by 1H NMR. However, pyrolysis of a mixture of 1 and D2Os3(CO)9(μ3,η2-C6D3CD3) (2-d8) gives 2 which is also just partially deuterated in all proton sites. Thus, intermolecular hydrogen/deuterium exchange accompanies the benzylidyne/methylbenzene interconversion." @default.
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- W2052783457 date "1988-01-01" @default.
- W2052783457 modified "2023-09-23" @default.
- W2052783457 title "Interconversion of benzylidyne and methylbenzyne triosmium complexes" @default.
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- W2052783457 doi "https://doi.org/10.1016/s0277-5387(00)86316-0" @default.
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