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- W2052803943 abstract "Abstract Fungi can degrade free fatty acids and triacylglycerols to provide a carbon and energy source. Medium chain fatty acids (those with a carbon length between six and 12 carbon atoms) are relatively uncommon. They are found in three oils of commercial importance—coconut, palm kernel and butter. The ability of fungi to convert medium chain fatty acids or triacylglycerols containing these acids to methyl ketones one carbon atom less has been known for a long time. Five genera can undertake these bioconversions—Aspergillus and Penicillium, and their corresponding teleomorphic genera Trichoderma, Cladosporium and Fusarium. Medium chain fatty acids inhibit fungal growth. The degree of inhibition depends on the concentration of the un-ionised acids. A number of fungal bioconversions of medium chain fatty acids can occur leading to the production of volatile metabolites. These include a partial β-oxidation to give the methyl ketone one carbon atom less than the parent fatty acid, reduction of the ketone to give the secondary alcohol, hydroxylation of the ketone to give a mono-hydroxy ketone, esterification and decarboxylation. It is suggested that the production of these volatile metabolites is a fungal strategy to eliminate metabolites which would otherwise be toxic." @default.
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- W2052803943 date "1993-01-01" @default.
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- W2052803943 title "Fungal strategies for detoxification of medium chain fatty acids" @default.
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- W2052803943 doi "https://doi.org/10.1016/0964-8305(93)90053-5" @default.
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