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• W2052807825 endingPage "483" @default.
• W2052807825 startingPage "476" @default.
• W2052807825 abstract "The stereochemical course of the singlet-oxygen ene reaction with acyclic olefins may be controlled if in the substrate conformational fixation (1,3-allylic strain) an allyl-ic substituent for interaction with the attacking oxygen enophile aligns. Various substrates were chosen to elucidate the features of the olefin that are necessary to control the sense (threo versus erythro) and the extent of the ii-facial preference of the singlet-oxygen attack. Depending on the electronic properties of the double bond and the nature of the allylic substituent, threo or erythro selectivity may be imposed through hydrogen bonding, electrostatic and steric effects and stereoelectronic alignment. Such directing properties, especially that of the hydroxy group, were also confirmed in the other reaction modes of singlet oxygen, namely the [4+2] cycloaddition to chiral naphthylenic alcohols and the [2+2] cycloaddition to an adamantylidene-substituted allylic alcohol. The syntheses of the natural products Merucathin and Iso-dihydromahubanolide B are two examples in which such stereocontrolled photooxygenations have been used as key steps to build up the required chirality diastereose-lectively." @default.
• W2052807825 created "2016-06-24" @default.
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• W2052807825 creator A5076972244 @default.
• W2052807825 creator A5077571045 @default.
• W2052807825 date "1999-10-01" @default.
• W2052807825 modified "2023-10-11" @default.
• W2052807825 title "Stereocontrolled Photooxygenations–A Valuable Synthetic Tool" @default.
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• W2052807825 doi "https://doi.org/10.1111/j.1751-1097.1999.tb08241.x" @default.
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