Matches in SemOpenAlex for { <https://semopenalex.org/work/W2052809534> ?p ?o ?g. }
Showing items 1 to 95 of
95
with 100 items per page.
- W2052809534 endingPage "3405" @default.
- W2052809534 startingPage "3402" @default.
- W2052809534 abstract "Nucleophilic substitution between the 4'-benzoyloxy derivative of cordycepin (3'-deoxyadenosine) and AlMe(3) proceeds mostly with retention of configuration at the 4'-position: the 4'-benzoyloxy substrate having the beta-d-configuration (8a) gave the 4'-methylated beta-d-nucleoside (9a) with a high diastereomeric excess, while the substrate 8b having the opposite 4'-configuration gave the corresponding alpha-l-isomer (9b) with a comparatively lower stereoselectivity. The S(N)i mechanism is proposed for this reaction (from 8 to 9). The polarity of the solvent has a significant influence on the stereoselectivity, especially for the formation of 9b." @default.
- W2052809534 created "2016-06-24" @default.
- W2052809534 creator A5031697973 @default.
- W2052809534 creator A5038992719 @default.
- W2052809534 creator A5069197165 @default.
- W2052809534 creator A5076912310 @default.
- W2052809534 date "2009-04-03" @default.
- W2052809534 modified "2023-09-26" @default.
- W2052809534 title "Solvent Effect Observed in Nucleophilic Substitution of 4′-(Benzoyloxy)cordycepin with AlMe<sub>3</sub>: Stereochemical Evidence for S<sub>N</sub>i Mechanism" @default.
- W2052809534 cites W1964469730 @default.
- W2052809534 cites W1976684786 @default.
- W2052809534 cites W1987116107 @default.
- W2052809534 cites W2022640413 @default.
- W2052809534 cites W2024550307 @default.
- W2052809534 cites W2086577689 @default.
- W2052809534 cites W2089179102 @default.
- W2052809534 cites W2952859938 @default.
- W2052809534 cites W1972201263 @default.
- W2052809534 doi "https://doi.org/10.1021/jo900289h" @default.
- W2052809534 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/19344163" @default.
- W2052809534 hasPublicationYear "2009" @default.
- W2052809534 type Work @default.
- W2052809534 sameAs 2052809534 @default.
- W2052809534 citedByCount "8" @default.
- W2052809534 countsByYear W20528095342012 @default.
- W2052809534 countsByYear W20528095342013 @default.
- W2052809534 countsByYear W20528095342014 @default.
- W2052809534 countsByYear W20528095342017 @default.
- W2052809534 crossrefType "journal-article" @default.
- W2052809534 hasAuthorship W2052809534A5031697973 @default.
- W2052809534 hasAuthorship W2052809534A5038992719 @default.
- W2052809534 hasAuthorship W2052809534A5069197165 @default.
- W2052809534 hasAuthorship W2052809534A5076912310 @default.
- W2052809534 hasConcept C111368507 @default.
- W2052809534 hasConcept C127313418 @default.
- W2052809534 hasConcept C132439834 @default.
- W2052809534 hasConcept C135731615 @default.
- W2052809534 hasConcept C138716334 @default.
- W2052809534 hasConcept C155647269 @default.
- W2052809534 hasConcept C161790260 @default.
- W2052809534 hasConcept C178790620 @default.
- W2052809534 hasConcept C178907741 @default.
- W2052809534 hasConcept C181199279 @default.
- W2052809534 hasConcept C181647583 @default.
- W2052809534 hasConcept C185592680 @default.
- W2052809534 hasConcept C2776543447 @default.
- W2052809534 hasConcept C2777289219 @default.
- W2052809534 hasConcept C2780066241 @default.
- W2052809534 hasConcept C2780471494 @default.
- W2052809534 hasConcept C2780636463 @default.
- W2052809534 hasConcept C55493867 @default.
- W2052809534 hasConcept C71240020 @default.
- W2052809534 hasConcept C95081189 @default.
- W2052809534 hasConceptScore W2052809534C111368507 @default.
- W2052809534 hasConceptScore W2052809534C127313418 @default.
- W2052809534 hasConceptScore W2052809534C132439834 @default.
- W2052809534 hasConceptScore W2052809534C135731615 @default.
- W2052809534 hasConceptScore W2052809534C138716334 @default.
- W2052809534 hasConceptScore W2052809534C155647269 @default.
- W2052809534 hasConceptScore W2052809534C161790260 @default.
- W2052809534 hasConceptScore W2052809534C178790620 @default.
- W2052809534 hasConceptScore W2052809534C178907741 @default.
- W2052809534 hasConceptScore W2052809534C181199279 @default.
- W2052809534 hasConceptScore W2052809534C181647583 @default.
- W2052809534 hasConceptScore W2052809534C185592680 @default.
- W2052809534 hasConceptScore W2052809534C2776543447 @default.
- W2052809534 hasConceptScore W2052809534C2777289219 @default.
- W2052809534 hasConceptScore W2052809534C2780066241 @default.
- W2052809534 hasConceptScore W2052809534C2780471494 @default.
- W2052809534 hasConceptScore W2052809534C2780636463 @default.
- W2052809534 hasConceptScore W2052809534C55493867 @default.
- W2052809534 hasConceptScore W2052809534C71240020 @default.
- W2052809534 hasConceptScore W2052809534C95081189 @default.
- W2052809534 hasIssue "9" @default.
- W2052809534 hasLocation W20528095341 @default.
- W2052809534 hasLocation W20528095342 @default.
- W2052809534 hasOpenAccess W2052809534 @default.
- W2052809534 hasPrimaryLocation W20528095341 @default.
- W2052809534 hasRelatedWork W1980193337 @default.
- W2052809534 hasRelatedWork W2015449942 @default.
- W2052809534 hasRelatedWork W2022736016 @default.
- W2052809534 hasRelatedWork W2032240280 @default.
- W2052809534 hasRelatedWork W2042277837 @default.
- W2052809534 hasRelatedWork W2052809534 @default.
- W2052809534 hasRelatedWork W2064457335 @default.
- W2052809534 hasRelatedWork W2067615050 @default.
- W2052809534 hasRelatedWork W2810355132 @default.
- W2052809534 hasRelatedWork W836805595 @default.
- W2052809534 hasVolume "74" @default.
- W2052809534 isParatext "false" @default.
- W2052809534 isRetracted "false" @default.
- W2052809534 magId "2052809534" @default.
- W2052809534 workType "article" @default.