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- W2052811010 abstract "Stereoselectivity of allylboration of 4-formyl[2.2]paracyclophane, 4-acetyl[2.2]paracyclophane, and 4-hydroxy-5-formyl[2.2]paracyclophane was studied and the relative configurations of the homoallylic alcohols obtained were established. Optically pure (Sp,Sc)-(+)-4-(4-hydroxy-1-methylbut-3-enyl)[2.2]paracyclophane and (Rc,Sc)-(+)-4-hydroxy-5-(4-hydroxybut-3-enyl)[2.2]paracyclophane were synthesized. The possibility of using (Sp,Sc)-(+)-4-(4-hydroxy-4-methylbut-3-enyl)[2.2]paracyclophane as a recoverable chiral auxiliary in asymmetric allylboration of aldehydes was demonstrated." @default.
- W2052811010 created "2016-06-24" @default.
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- W2052811010 date "2010-05-31" @default.
- W2052811010 modified "2023-09-25" @default.
- W2052811010 title "ChemInform Abstract: Stereoselective Synthesis of Homoallylic Alcohols of the [2.2]Paracyclophane Series and Their Use as Auxiliaries in Asymmetric Allylboration of Aldehydes." @default.
- W2052811010 cites W2952127175 @default.
- W2052811010 doi "https://doi.org/10.1002/chin.200046040" @default.
- W2052811010 hasPublicationYear "2010" @default.
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