Matches in SemOpenAlex for { <https://semopenalex.org/work/W2052813095> ?p ?o ?g. }
- W2052813095 endingPage "4251" @default.
- W2052813095 startingPage "4240" @default.
- W2052813095 abstract "The synthesis and characterization of a family of para-functionalized complexes 3a−k, [(η2-dppe)(η5-C5Me5)Fe(C⋮CC6H4X)] (dppe = 1,2-(diphenylphosphino)ethane; X = NO2, CN, CF3, F, Br, H, Me, tBu, OMe, NH2, NMe2), is reported. Most of the complexes were obtained in fair yields from the terminal iron acetylide complex [(η2-dppe)(η5-C5Me5)Fe(C⋮CH)] (1) using a palladium/copper-catalyzed coupling reaction. The complex 3j, with a strongly electron releasing NH2 group, was synthesized by the more classical vinylidene route. The corresponding thermally stable radical cations could be generated in solution by addition of [(η5-C5H5)2Fe+][PF6-] from 3a−k and characterized by infrared spectroscopy. Selected examples of these iron(III) salts (3a, X = NO2; 3f, X = H; 3j, X = NH2) were isolated and more completely characterized by Mössbauer spectroscopy. Crystal structures were determined for (η2-dppe)(η5-C5Me5)Fe[C⋮C-1,4-(C6H4)-NO2] (3a), (η2-dppe)(η5-C5Me5)Fe(C⋮C-1,4-(C6H4)-CN] (3b), (η2-dppe)(η5-C5Me5)Fe[C⋮C−(C6H5)] (3f), and [(η2-dppe)(η5-C5Me5)Fe{C⋮C-1,4-(C6H4)NO2}+][PF6-] (3a+PF6-)." @default.
- W2052813095 created "2016-06-24" @default.
- W2052813095 creator A5012681142 @default.
- W2052813095 creator A5023327466 @default.
- W2052813095 creator A5031940986 @default.
- W2052813095 creator A5048552245 @default.
- W2052813095 date "2000-09-09" @default.
- W2052813095 modified "2023-10-07" @default.
- W2052813095 title "Electron-Rich Piano-Stool Iron σ-Acetylides Bearing a Functional Aryl Group. Synthesis and Characterization of Iron(II) and Iron(III) Complexes" @default.
- W2052813095 cites W1964432819 @default.
- W2052813095 cites W1974321885 @default.
- W2052813095 cites W1981135592 @default.
- W2052813095 cites W1982570231 @default.
- W2052813095 cites W1990608394 @default.
- W2052813095 cites W1993743351 @default.
- W2052813095 cites W1999718442 @default.
- W2052813095 cites W2000806165 @default.
- W2052813095 cites W2002764261 @default.
- W2052813095 cites W2010275163 @default.
- W2052813095 cites W2019624118 @default.
- W2052813095 cites W2025039040 @default.
- W2052813095 cites W2027467909 @default.
- W2052813095 cites W2036693504 @default.
- W2052813095 cites W2047935418 @default.
- W2052813095 cites W2050750527 @default.
- W2052813095 cites W2054084566 @default.
- W2052813095 cites W2056097813 @default.
- W2052813095 cites W2061926693 @default.
- W2052813095 cites W2063074480 @default.
- W2052813095 cites W2068957581 @default.
- W2052813095 cites W2075571981 @default.
- W2052813095 cites W2095653105 @default.
- W2052813095 cites W2098006832 @default.
- W2052813095 cites W2157495221 @default.
- W2052813095 cites W2315424832 @default.
- W2052813095 cites W2319004313 @default.
- W2052813095 cites W274377105 @default.
- W2052813095 cites W2953024617 @default.
- W2052813095 cites W4231960227 @default.
- W2052813095 doi "https://doi.org/10.1021/om000325o" @default.
- W2052813095 hasPublicationYear "2000" @default.
- W2052813095 type Work @default.
- W2052813095 sameAs 2052813095 @default.
- W2052813095 citedByCount "124" @default.
- W2052813095 countsByYear W20528130952012 @default.
- W2052813095 countsByYear W20528130952013 @default.
- W2052813095 countsByYear W20528130952014 @default.
- W2052813095 countsByYear W20528130952015 @default.
- W2052813095 countsByYear W20528130952016 @default.
- W2052813095 countsByYear W20528130952017 @default.
- W2052813095 countsByYear W20528130952018 @default.
- W2052813095 countsByYear W20528130952019 @default.
- W2052813095 countsByYear W20528130952020 @default.
- W2052813095 countsByYear W20528130952021 @default.
- W2052813095 countsByYear W20528130952022 @default.
- W2052813095 crossrefType "journal-article" @default.
- W2052813095 hasAuthorship W2052813095A5012681142 @default.
- W2052813095 hasAuthorship W2052813095A5023327466 @default.
- W2052813095 hasAuthorship W2052813095A5031940986 @default.
- W2052813095 hasAuthorship W2052813095A5048552245 @default.
- W2052813095 hasConcept C107031643 @default.
- W2052813095 hasConcept C115624301 @default.
- W2052813095 hasConcept C153642686 @default.
- W2052813095 hasConcept C155647269 @default.
- W2052813095 hasConcept C178790620 @default.
- W2052813095 hasConcept C185592680 @default.
- W2052813095 hasConcept C2779627003 @default.
- W2052813095 hasConcept C2780263894 @default.
- W2052813095 hasConcept C2781076698 @default.
- W2052813095 hasConcept C544153396 @default.
- W2052813095 hasConcept C544778455 @default.
- W2052813095 hasConcept C70854507 @default.
- W2052813095 hasConcept C71240020 @default.
- W2052813095 hasConcept C8010536 @default.
- W2052813095 hasConceptScore W2052813095C107031643 @default.
- W2052813095 hasConceptScore W2052813095C115624301 @default.
- W2052813095 hasConceptScore W2052813095C153642686 @default.
- W2052813095 hasConceptScore W2052813095C155647269 @default.
- W2052813095 hasConceptScore W2052813095C178790620 @default.
- W2052813095 hasConceptScore W2052813095C185592680 @default.
- W2052813095 hasConceptScore W2052813095C2779627003 @default.
- W2052813095 hasConceptScore W2052813095C2780263894 @default.
- W2052813095 hasConceptScore W2052813095C2781076698 @default.
- W2052813095 hasConceptScore W2052813095C544153396 @default.
- W2052813095 hasConceptScore W2052813095C544778455 @default.
- W2052813095 hasConceptScore W2052813095C70854507 @default.
- W2052813095 hasConceptScore W2052813095C71240020 @default.
- W2052813095 hasConceptScore W2052813095C8010536 @default.
- W2052813095 hasIssue "21" @default.
- W2052813095 hasLocation W20528130951 @default.
- W2052813095 hasOpenAccess W2052813095 @default.
- W2052813095 hasPrimaryLocation W20528130951 @default.
- W2052813095 hasRelatedWork W1514832481 @default.
- W2052813095 hasRelatedWork W1896524699 @default.
- W2052813095 hasRelatedWork W1985933127 @default.
- W2052813095 hasRelatedWork W2053927781 @default.
- W2052813095 hasRelatedWork W2054084566 @default.
- W2052813095 hasRelatedWork W2060254969 @default.