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- W2052871736 abstract "Abstract The photolysis of α-alkoxycyclohexanones and α-alkoxycyclopentanones in ethanol involves NII elimination of an alkoxy group. The proportion of cyclanone is higher when starting from α-alkoxycyclohexanones, and esters are isolated in low yields. No ester, but aldehydes are obtained from α-alkoxycyclopentanones. By photolysis of 2-methoxy norbornanone, only epimerisation is detected. Oxetanols are formed with satisfactory yields only from aromatic ketones such as α-methoxy tetralone or α-methoxyindanone. Mechanistic aspects, including the nature of the excited states, are discussed." @default.
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- W2052871736 date "1975-01-01" @default.
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- W2052871736 title "Photolyse d'α-alcoxycyclanones" @default.
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