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- W2052911530 abstract "The geometries of three conformations of methyl hydrazine were refined without constraints by ab initio calculations on the 4–21 G level using Pulay's force method and our normal coordinate force relaxation procedure. The most stable conformation is one in which the C-N bond can interact with the adjacent lone pair on nitrogen. A large number of the structural details calculated are in complete agreement with qualitative predictions based on the anomeric orbital interaction model for organic systems with electron lone pairs." @default.
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- W2052911530 date "2010-09-01" @default.
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- W2052911530 title "Ab initio studies of structural features not easily amenable to experiment: 9. molecular structure and conformational analysis of hydrazine and methyl-hydrazine" @default.
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- W2052911530 doi "https://doi.org/10.1002/bscb.19800890906" @default.
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