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- W2052981036 abstract "Abstract To investigate the non-linear optical properties of nitrophenylhydrazones, a series of 4-nitro- and 2,4-dinitrophenylhydrazones of substituted aromatic aldehydes were synthesized. It was found that many of the dinitrophenythydrazone derivatives are liquid-crystalline and X-ray investigations show that the mesophase corresponds to a hexagonal columnar structure. To explain this unusual behaviour it is necessary to assume that a mesogenic structure is formed by intramolecular hydrogen bonding of the dinitrophenylhydrazones. Charge transfer induced antiparallel alignment of these moleculer dipoles leads to discoid structures, forming the columnar phases." @default.
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- W2052981036 date "1991-06-01" @default.
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- W2052981036 title "Columnar phases from semi-discoid molecules. Phase induction via hydrogen bonding and charge transfer interactions" @default.
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- W2052981036 doi "https://doi.org/10.1080/02678299108055003" @default.
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