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- W2052983493 abstract "The alkylidyne complex [W((CR)(CO)2(η-C5H5)] (I) R C6H4Me-4) reacts with [Co2(CO)6 (μ-⊥-PhC2H)] in refluxing hexane to give the trinuclear cluster [Co2W(η3-PCCCHCR)(η-CO)(CO)5(η-C5H5)] (II), which has been characterized by X-ray diffraction. By contrast, the reaction of I with [Co2(CO)6(μ-⊥-R′C2R″)] (R′ R″ Ph; R′ tBut, R″ H) resulted, mainly, in the formation of the ditungstatetrahedrane complex [W2(μ-⊥-C2R2)()CO)4(η-C5H5)2], and for R′ R″ SiMe3 this dimerization was found to be catalytic." @default.
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- W2052983493 date "1989-02-01" @default.
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- W2052983493 title "The reactions of the alkylidyne complex [W(CR(CO)2(η-C5H5)] with dicobaltatetrahedranes. Crystal structure of [Co2W(μ3PhCCHCR) (μ-CO)(CO)5(η-C5H5)] · H2O (R C6H4Me-4)" @default.
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- W2052983493 doi "https://doi.org/10.1016/0022-328x(89)85385-9" @default.
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