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- W2052985565 abstract "n-Heptane/urea is an aperiodic inclusion compound in which the ratio of host and guest repeats along the channel axis is very close to unity and is found to have a constant value (0.981) from 280 K to 90 K. Below 280 K, two phase transitions are observed. The first (T(c1) = 145 K) is a ferroelastic phase transition that generates superstructure reflections for the host while leaving the guest with 1D order. The second (T(c2) = 130 K) is a phase ordering transition to a four-dimensional structure (P2(1)11(0βγ)) with pronounced host-guest intermodulation and a temperature dependent phase shift between guests in adjacent channels." @default.
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- W2052985565 date "2012-03-14" @default.
- W2052985565 modified "2023-10-10" @default.
- W2052985565 title "A molecular “phase ordering” phase transition leading to a modulated aperiodic composite in <i>n</i>-heptane/urea" @default.
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- W2052985565 doi "https://doi.org/10.1063/1.3692329" @default.
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