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- W2053004911 abstract "Platinum(II)-olefin complexes with Schiff bases derived from 2-acetylthiophene, and primary amines were synthesized and characterized on the basis of elemental analysis, I.R., 1H, 13C, and 195Pt-NMR studies. The Schiff bases behave as unidentate bases with N as the only donor ligand and form four coordinate complexes with 1:1 metal-ligand stoichiometry at ambient temperature of composition trans-[PtCl2(η2-C2H4)(Imine)]. Long-range coupling constants were observed between different protons of the imine and platinum-195. Addition of excess amine leads to displacement of the imine and rapidly gives the zwitterionic 2-ammonioethanide-platinum(II) complex. The platinum complex of the imine type provide the first example of stable platinum(II)-olefin-monodentate σ-imine bonded complexes. In addition, 1H, 13C and 195Pt-NMR spectra show that only a single rotamer exists. Other more imine complexes were synthesized." @default.
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- W2053004911 date "1984-10-01" @default.
- W2053004911 modified "2023-10-18" @default.
- W2053004911 title "Multinuclear NMR studies on new platinum imine complexes" @default.
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- W2053004911 doi "https://doi.org/10.1016/s0020-1693(00)82430-5" @default.
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