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- W2053006245 abstract "The local octahedral environments of the impurity ions in the ZnSiF6·6H2O: Mn2+ (or Ni2+) crystals with small axial (trigonal) distortions have been studied by analyzing their EPR spectra. According to the study, an interesting trend is suggested, i.e. the sign of the zero-field splitting (ZFS) D is in close relationship with the local structural distortions (elongation or compression) of the octahedral environment of the impurity ions. Thus, the bonding angles of distortions of the octahedral environments at low temperatures (4.2 K) are determined as θ − θoh ≈ 0.344° and 0.055° for ZnSiF6 · 6H2O: Mn2+ and ZnSiF6 · 6H2O: Ni2+, respectively." @default.
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- W2053006245 date "1996-05-01" @default.
- W2053006245 modified "2023-10-01" @default.
- W2053006245 title "Investigation of the trigonal-field splittings D and dependences on the local structural distortions for ZnSiF6·6H2O: Mn2+ (Ni2+)" @default.
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- W2053006245 doi "https://doi.org/10.1016/0921-4526(96)00013-0" @default.
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