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• W2053018665 startingPage "14388" @default.
• W2053018665 abstract "In reactions with benzene and related substrates, an oxazole-based superelectrophile is found to be significantly more reactive than a related monocationic species. Theoretical calculations estimate that the lowest unoccupied molecular orbital (LUMO) for the superelectrophile is about 4 eV lower in energy than the LUMOs of comparable monocations. When the oxazole-based superelectrophile is reacted with ferrocene, a dimeric product is formed in high yield. The dimerization occurs by a single electron transfer reaction between the dicationic superelectrophile and ferrocene, followed by coupling of the radical cations." @default.
• W2053018665 created "2016-06-24" @default.
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• W2053018665 date "2008-10-08" @default.
• W2053018665 modified "2023-09-26" @default.
• W2053018665 title "<i>N</i>-Heterocyclic Superelectrophiles and Evidence for Single Electron Transfer Chemistry" @default.
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• W2053018665 doi "https://doi.org/10.1021/ja8062953" @default.
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