FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053101039> ?p ?o ?g. }

• W2053101039 endingPage "1516" @default.
• W2053101039 startingPage "1506" @default.
• W2053101039 abstract "The reactivity of a solvated electron with MgII salts in THF is investigated by pulse radiolysis. With magnesium chloride, no reaction is observed, but when magnesium perchlorate is used, the solvated electron reacts to form a species absorbing in the near-infrared. Conductivity measurements show that neither MgCl2 nor Mg(ClO4)2 is dissociated in THF. Quantum chemical calculations show that the difference in behavior between the two salts can be traced back to the electron affinities of the solutes in the gas phase. The solvated electron forms a stable pair only with magnesium perchlorate. The structure of this pair is proposed. The rate constants of the reactions and the extinction coefficients of the different species involved in the formation and decay of the pair are determined with a probabilistic global analysis method of the time-resolved absorbance signals." @default.
• W2053101039 created "2016-06-24" @default.
• W2053101039 creator A5027274609 @default.
• W2053101039 creator A5066826017 @default.
• W2053101039 creator A5074220252 @default.
• W2053101039 creator A5076633465 @default.
• W2053101039 creator A5089273442 @default.
• W2053101039 date "2003-02-19" @default.
• W2053101039 modified "2023-10-18" @default.
• W2053101039 title "Solvated Electron Pairing with Earth Alkaline Metals in THF. 1. Formation and Structure of the Pair with Divalent Magnesium" @default.
• W2053101039 cites W1968625379 @default.
• W2053101039 cites W1983612150 @default.
• W2053101039 cites W1987765885 @default.
• W2053101039 cites W1995267105 @default.
• W2053101039 cites W1998523300 @default.
• W2053101039 cites W2001346987 @default.
• W2053101039 cites W2002276735 @default.
• W2053101039 cites W2014063669 @default.
• W2053101039 cites W2015759883 @default.
• W2053101039 cites W2022708814 @default.
• W2053101039 cites W2024315245 @default.
• W2053101039 cites W2027027575 @default.
• W2053101039 cites W2047833144 @default.
• W2053101039 cites W2051959027 @default.
• W2053101039 cites W2067980310 @default.
• W2053101039 cites W2078775282 @default.
• W2053101039 cites W2079425270 @default.
• W2053101039 cites W2082793377 @default.
• W2053101039 cites W2087952744 @default.
• W2053101039 cites W2088235037 @default.
• W2053101039 cites W2097281583 @default.
• W2053101039 cites W2122185129 @default.
• W2053101039 cites W2169850114 @default.
• W2053101039 cites W2328925659 @default.
• W2053101039 cites W326779441 @default.
• W2053101039 cites W4247690662 @default.
• W2053101039 cites W4249529907 @default.
• W2053101039 cites W4292403327 @default.
• W2053101039 cites W978283045 @default.
• W2053101039 doi "https://doi.org/10.1021/jp0216124" @default.
• W2053101039 hasPublicationYear "2003" @default.
• W2053101039 type Work @default.
• W2053101039 sameAs 2053101039 @default.
• W2053101039 citedByCount "21" @default.
• W2053101039 countsByYear W20531010392012 @default.
• W2053101039 countsByYear W20531010392013 @default.
• W2053101039 countsByYear W20531010392014 @default.
• W2053101039 countsByYear W20531010392015 @default.
• W2053101039 countsByYear W20531010392016 @default.
• W2053101039 countsByYear W20531010392018 @default.
• W2053101039 countsByYear W20531010392021 @default.
• W2053101039 countsByYear W20531010392022 @default.
• W2053101039 crossrefType "journal-article" @default.
• W2053101039 hasAuthorship W2053101039A5027274609 @default.
• W2053101039 hasAuthorship W2053101039A5066826017 @default.
• W2053101039 hasAuthorship W2053101039A5074220252 @default.
• W2053101039 hasAuthorship W2053101039A5076633465 @default.
• W2053101039 hasAuthorship W2053101039A5089273442 @default.
• W2053101039 hasConcept C121332964 @default.
• W2053101039 hasConcept C142724271 @default.
• W2053101039 hasConcept C145148216 @default.
• W2053101039 hasConcept C147120987 @default.
• W2053101039 hasConcept C147789679 @default.
• W2053101039 hasConcept C178790620 @default.
• W2053101039 hasConcept C179104552 @default.
• W2053101039 hasConcept C184651966 @default.
• W2053101039 hasConcept C185592680 @default.
• W2053101039 hasConcept C196609583 @default.
• W2053101039 hasConcept C198091228 @default.
• W2053101039 hasConcept C204787440 @default.
• W2053101039 hasConcept C2776910235 @default.
• W2053101039 hasConcept C2780709120 @default.
• W2053101039 hasConcept C42296456 @default.
• W2053101039 hasConcept C43617362 @default.
• W2053101039 hasConcept C543218039 @default.
• W2053101039 hasConcept C62520636 @default.
• W2053101039 hasConcept C62715864 @default.
• W2053101039 hasConcept C66887884 @default.
• W2053101039 hasConcept C71924100 @default.
• W2053101039 hasConcept C98015330 @default.
• W2053101039 hasConceptScore W2053101039C121332964 @default.
• W2053101039 hasConceptScore W2053101039C142724271 @default.
• W2053101039 hasConceptScore W2053101039C145148216 @default.
• W2053101039 hasConceptScore W2053101039C147120987 @default.
• W2053101039 hasConceptScore W2053101039C147789679 @default.
• W2053101039 hasConceptScore W2053101039C178790620 @default.
• W2053101039 hasConceptScore W2053101039C179104552 @default.
• W2053101039 hasConceptScore W2053101039C184651966 @default.
• W2053101039 hasConceptScore W2053101039C185592680 @default.
• W2053101039 hasConceptScore W2053101039C196609583 @default.
• W2053101039 hasConceptScore W2053101039C198091228 @default.
• W2053101039 hasConceptScore W2053101039C204787440 @default.
• W2053101039 hasConceptScore W2053101039C2776910235 @default.
• W2053101039 hasConceptScore W2053101039C2780709120 @default.
• W2053101039 hasConceptScore W2053101039C42296456 @default.
• W2053101039 hasConceptScore W2053101039C43617362 @default.
• W2053101039 hasConceptScore W2053101039C543218039 @default.
• W2053101039 hasConceptScore W2053101039C62520636 @default.

• next