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• W2053102595 startingPage "1840" @default.
• W2053102595 abstract "Abstract Biuretooxophosphates represent a link between carbon nitride and phosphorus (oxo)nitride precursor chemistry being closely related to cyanurates and trimetaphosphimates. The group of alkali biuretooxophosphates has been complemented by the synthesis of four salts M[PO 2 (NH) 3 (CO) 2 ] · x H 2 O in which M = Li, K, Rb, and Cs ( x = 1, 0, 0.5, 0, respectively). The structures were solved by single‐crystal X‐ray diffraction and compared with the corresponding ammonium and sodium salts. For all of the salts, the 1‐phospha‐2,4,6‐ s ‐triazine ring exhibits a nearly planar conformation with the phosphorus atom being slightly deflected. In the sequence Li to Cs, the crystal structures show a significant change in orientation leading from a parallel to a perpendicular arrangement of the rings, the latter being bridged by N–H ··· O bonds. The thermal behavior of the biuretooxophosphates was examined by means of temperature‐dependent powder X‐ray diffraction measurements and combined thermogravimetric analysis (TGA) and differential thermal analysis (DTA). Moreover, the FTIR and photoluminescence spectra of the salts are discussed." @default.
• W2053102595 created "2016-06-24" @default.
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• W2053102595 date "2012-02-27" @default.
• W2053102595 modified "2023-10-16" @default.
• W2053102595 title "A Systematic Approach to Alkali Biuretooxophosphates" @default.
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• W2053102595 doi "https://doi.org/10.1002/ejic.201101317" @default.
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