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- W2053114023 abstract "Abstract The defect structure of lanthanum-modified lead-zirconate-titanate (PLZT) is altered by annealing at 700 °C in different reducing atmospheres and studied by conductivity measurements, different spectroscopic techniques and determination of the thermally stimulated depolarization current (TSDC). It is found that annealing at an oxygen partial pressure of p O 2 10 − 16 bar leads to the formation of oxygen vacancies V O • • or V O × . If hydrogen is present in the reducing atmosphere, it can be incorporated as either H O • or OH O • . The defects can be evidenced in both the IR and UV/VIS absorption spectra. Additionally, high levels of reduction cause a shift in the Fermi level, leading to the population of intrinsic Fe impurities, which can possibly be utilized as photorefractive centers." @default.
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- W2053114023 date "2012-11-01" @default.
- W2053114023 modified "2023-10-12" @default.
- W2053114023 title "Influence of reducing atmosphere on the defect chemistry of lead lanthanum zirconate titanate (8/65/35)" @default.
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- W2053114023 doi "https://doi.org/10.1016/j.ssi.2012.09.003" @default.
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