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- W2053157033 endingPage "12289" @default.
- W2053157033 startingPage "12280" @default.
- W2053157033 abstract "The intramolecular frustrated Lewis pair (mesityl)2P−CH2−CH2−B(C6F5)2 was generated in situ by HB(C6F5)2 hydroboration of dimesitylvinylphosphine. The compound reacts with 1-pentyne by C−H bond cleavage. It undergoes a 1,2-addition to the carbonyl group of trans-cinnamic aldehyde to yield a zwitterionic six-membered heterocycle by B−O and P−C bond formation. The Lewis pair regioselectively adds to the electron-rich C═C double bond of ethyl vinyl ether, and it selectively undergoes an exo-cis-2,3-addition to norbornene. A combined experimental/theoretical study suggests that this reaction takes place in an asynchronous concerted fashion with the B−C bond being formed in slight preference to the P−C bond. The addition products were characterized by X-ray crystal structure analyses." @default.
- W2053157033 created "2016-06-24" @default.
- W2053157033 creator A5012922538 @default.
- W2053157033 creator A5034807035 @default.
- W2053157033 creator A5039921470 @default.
- W2053157033 creator A5042863303 @default.
- W2053157033 creator A5048542589 @default.
- W2053157033 creator A5052504260 @default.
- W2053157033 date "2009-08-06" @default.
- W2053157033 modified "2023-10-12" @default.
- W2053157033 title "Reactions of an Intramolecular Frustrated Lewis Pair with Unsaturated Substrates: Evidence for a Concerted Olefin Addition Reaction" @default.
- W2053157033 cites W1964740687 @default.
- W2053157033 cites W1966094041 @default.
- W2053157033 cites W1967571454 @default.
- W2053157033 cites W1969248706 @default.
- W2053157033 cites W1969321380 @default.
- W2053157033 cites W1971242245 @default.
- W2053157033 cites W1975306798 @default.
- W2053157033 cites W1977206943 @default.
- W2053157033 cites W1977225494 @default.
- W2053157033 cites W1978849007 @default.
- W2053157033 cites W1980097507 @default.
- W2053157033 cites W1980543768 @default.
- W2053157033 cites W1982406806 @default.
- W2053157033 cites W1982458136 @default.
- W2053157033 cites W1984083274 @default.
- W2053157033 cites W1987753766 @default.
- W2053157033 cites W1989139015 @default.
- W2053157033 cites W1990756269 @default.
- W2053157033 cites W1992084666 @default.
- W2053157033 cites W1993200579 @default.
- W2053157033 cites W1994387604 @default.
- W2053157033 cites W1994567008 @default.
- W2053157033 cites W1996284236 @default.
- W2053157033 cites W1996397506 @default.
- W2053157033 cites W1996474150 @default.
- W2053157033 cites W1996558224 @default.
- W2053157033 cites W1997521799 @default.
- W2053157033 cites W2000412424 @default.
- W2053157033 cites W2000466466 @default.
- W2053157033 cites W2001916278 @default.
- W2053157033 cites W2002482043 @default.
- W2053157033 cites W2003128245 @default.
- W2053157033 cites W2005501378 @default.
- W2053157033 cites W2006363726 @default.
- W2053157033 cites W2008546219 @default.
- W2053157033 cites W2008844584 @default.
- W2053157033 cites W2010668831 @default.
- W2053157033 cites W2012134512 @default.
- W2053157033 cites W2013016373 @default.
- W2053157033 cites W2013468066 @default.
- W2053157033 cites W2014200671 @default.
- W2053157033 cites W2014576205 @default.
- W2053157033 cites W2017088934 @default.
- W2053157033 cites W2018923471 @default.
- W2053157033 cites W2019070167 @default.
- W2053157033 cites W2019286623 @default.
- W2053157033 cites W2020891256 @default.
- W2053157033 cites W2021224521 @default.
- W2053157033 cites W2021618258 @default.
- W2053157033 cites W2023184492 @default.
- W2053157033 cites W2026144804 @default.
- W2053157033 cites W2028022118 @default.
- W2053157033 cites W2028528592 @default.
- W2053157033 cites W2030380295 @default.
- W2053157033 cites W2031346144 @default.
- W2053157033 cites W2037577788 @default.
- W2053157033 cites W2037935642 @default.
- W2053157033 cites W2039396938 @default.
- W2053157033 cites W2039717185 @default.
- W2053157033 cites W2041815809 @default.
- W2053157033 cites W2042739813 @default.
- W2053157033 cites W2044591029 @default.
- W2053157033 cites W2055563809 @default.
- W2053157033 cites W2057344624 @default.
- W2053157033 cites W2058210956 @default.
- W2053157033 cites W2060079271 @default.
- W2053157033 cites W2060137387 @default.
- W2053157033 cites W2064518449 @default.
- W2053157033 cites W2069305408 @default.
- W2053157033 cites W2069868352 @default.
- W2053157033 cites W2071033467 @default.
- W2053157033 cites W2071085919 @default.
- W2053157033 cites W2072534520 @default.
- W2053157033 cites W2074225716 @default.
- W2053157033 cites W2075027556 @default.
- W2053157033 cites W2075903690 @default.
- W2053157033 cites W2076766914 @default.
- W2053157033 cites W2077380199 @default.
- W2053157033 cites W2078277171 @default.
- W2053157033 cites W2081121958 @default.
- W2053157033 cites W2082273621 @default.
- W2053157033 cites W2084613668 @default.
- W2053157033 cites W2085060770 @default.
- W2053157033 cites W2085391573 @default.
- W2053157033 cites W2086458928 @default.
- W2053157033 cites W2088669975 @default.
- W2053157033 cites W2091687583 @default.