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- W2053157725 abstract "Recent published data on dissolved calcium in seawater reveal an apparent excess of calcium over that predicted from the changes in alkalinity. In the South Pacific this excess calcium is approximately 40 μmoles/kg. We suggest that this arises from an in-situ titration of some of the alkalinity by protons derived from the redox changes associated with oxidative decomposition of organic matter. This postulates an effective flux of nitric and phosphoric acids into the deep water. Other redox changes, such as in the oxidation of reduced sulfur, may also contribute protons, but these are more difficult to evaluate. This concept changes current thinking on the oceanic CO2-carbonate system. It increases the amount of calcium carbonate believed to have dissolved in the ocean by ca. 25%; and alters the proportions of abyssal CO2 believed to be derived from respiration versus carbonate dissolution by about 10%." @default.
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- W2053157725 date "1975-05-01" @default.
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- W2053157725 title "An oceanic calcium problem?" @default.
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- W2053157725 doi "https://doi.org/10.1016/0012-821x(75)90179-x" @default.
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