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- W2053159178 abstract "Abstract As shown by Milne in the early days of quantum mechanics, the non-relativistic binding energy of a heavy neutral atom with nuclear charge Ze is proportional to Z 7/3 in the large Z limit. Correction terms of order Z 2 and Z 5/3 to Milne’s limiting large Z result were first calculated by Scott. Here, the question as to the power of Z at which correlation energy first appears in such a binding energy formula is addressed. It is shown that a recent approximation proposed by one of us (AN) supports an earlier extrapolation from large dimensionality D to D = 3 by Herschbach and co-workers, that correlation energy enters the large Z binding energy formula for the first time at o( Z 4/3 )." @default.
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- W2053159178 date "2005-11-01" @default.
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- W2053159178 title "Non-relativistic binding energies of heavy neutral atoms: Dependence of correlation energy on atomic number" @default.
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- W2053159178 doi "https://doi.org/10.1016/j.cplett.2005.09.058" @default.
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