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- W2053164112 abstract "We present angle‐resolved photoemission results which indicate that the sensitivities of the surface states and resonances on W(110) and Mo(110) to hydrogen adsorption are substantially momentum dependent. Some bands are rapidly quenched by hydrogen adsorption, while others simply shift downward in energy by a fraction of an electron volt. This sensitivity has been observed to change abruptly within a given band. A simple analysis determines the hydrogen adsorption site to be at or near the long bridge on both surfaces. We propose that the larger shifts observed on W(110) indicate that the stable adsorption site lies closer to the surface, thereby inducing the observed (1×1) reconstruction. This difference may be a reflection of the greater importance of relativistic effects in the 5d relative to the 4d metals. The technique provides a general probe of hydrogen chemisorption which allows a link to be made between momentum space and real space and which will eventually allow an accurate determination of structural parameters." @default.
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- W2053164112 date "1989-05-01" @default.
- W2053164112 modified "2023-09-27" @default.
- W2053164112 title "Symmetry effects in hydrogen chemisorption electronic structure" @default.
- W2053164112 doi "https://doi.org/10.1116/1.575957" @default.
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