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- W2053188373 abstract "In this study,we have shown the applicability of electrophoretic deposition ( EPD ) for shape‐forming in Ti 3 SiC 2 —a representative MAX phase; and viability of texture development thereof by application of a strong magnetic field (12 T). The dispersion characteristics of Ti 3 SiC 2 suspension were investigated in terms of surface charge, rheological measurement, and adsorption study. Polyethyleneimine has been used as dispersant to stabilize the suspension. It was found that the iso‐electric point ( IEP ) of Ti 3 SiC 2 powder was pH IEP ~ 4. The surface charge of powder changed in presence of the Polyethyleneimine dispersant and IEP shifted significantly towards basic pH ~ 10. The shift in IEP has been quantified in terms of Δ G 0 SP , the specific free energy of adsorption between the surface sites and the adsorbing polyelectrolyte ( PEI ) (The value of Δ G 0 SP obtained is −9.521 RT units). The optimized suspension parameters for EPD were determined as 10 vol% Ti 3 SiC 2 and 1 dwb PEI in 50% ethanolic water at pH ~ 7. X ‐ray diffraction analysis of the textured samples developed, revealed that the preferred orientation of Ti 3 SiC 2 grains parallel to the magnetic field direction was along the a , b ‐axis (The Lotgering orientation factors on the textured top surface and textured side surface were determined as f L( hk 0) = 0.35 and f L(00 l ) = 0.75, respectively)." @default.
- W2053188373 created "2016-06-24" @default.
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- W2053188373 date "2012-06-04" @default.
- W2053188373 modified "2023-09-30" @default.
- W2053188373 title "Electrophoretic Deposition of Ti3SiC2 and Texture Development in a Strong Magnetic Field" @default.
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- W2053188373 doi "https://doi.org/10.1111/j.1551-2916.2012.05296.x" @default.
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