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• W2053209042 abstract "A series of addition cure poly(imide siloxane) resins were synthesized, incorporating various concentrations of α, ω-bis(3-aminopropyl) poly(dimethyl-diphenylsiloxanes), and α, ω-bis(p-aminophenyl) poly(dimethylsiloxane) into the formulated imide oligomer. Both carbon and glass fiber textile laminates were fabricated using amic acid and polymerization of monomer reactants (PMR) approaches. The cured composite laminates were subjected to an accelerated thermo-oxidative aging environment of 400°C for 100 h in air. Physical, thermal, and mechanical properties were evaluated to determine the structure-oxidative stability interrelationships. In general, composite mechanical properties were found to increase with increasing siloxane concentration in the matrix. Composite thermo-oxidative durability (measured via mass loss and mechanical property retention after oxidative aging) was improved through incorporation of diphenyl and diphenyl-dimethyl siloxane segments into the imide oligomer backbone up to ∼35% by weight aminosiloxane. Oxidative stability was found to be mostly dependent on the degree of phenyl substitution on the silicon atoms in the siloxane blocks, as compared to the moiety attaching the amine groups to the siloxane block. POLYM. COMPOS., 2008. © 2008 Society of Plastics Engineers" @default.
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• W2053209042 date "2008-06-01" @default.
• W2053209042 modified "2023-09-25" @default.
• W2053209042 title "Effect of matrix chemical structure on the thermo-oxidative stability of addition cure poly(imide siloxane) composites" @default.
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• W2053209042 doi "https://doi.org/10.1002/pc.20428" @default.
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