Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053275320> ?p ?o ?g. }
- W2053275320 endingPage "4325" @default.
- W2053275320 startingPage "4317" @default.
- W2053275320 abstract "Abstract The electronic structure and magnetic properties of the recently synthesized V IV /V V mixed‐valence alkoxo‐polyoxovanadate comprising a hexanuclear vanadium core with four unpaired electrons have been studied within the DFT framework. The results of calculations suggest that the d electrons are completely trapped within the hexavanadate core, in agreement with the experimental observations. The exchange coupling constants computed using the broken symmetry formalism appeared to be of a ferromagnetic nature. Such interactions are very rare in oxovanadium complexes and are a consequence of a specific core geometry imposed by the polyoxometalate architecture. It has been shown that the earlier proposed intramolecular electron transfer cannot change the ground spin‐state multiplicity irrespective of the sign of the exchange parameters.(© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2007)" @default.
- W2053275320 created "2016-06-24" @default.
- W2053275320 creator A5020930375 @default.
- W2053275320 creator A5027554432 @default.
- W2053275320 creator A5028535289 @default.
- W2053275320 creator A5051502997 @default.
- W2053275320 creator A5067485436 @default.
- W2053275320 date "2007-09-01" @default.
- W2053275320 modified "2023-10-10" @default.
- W2053275320 title "Ferromagnetic Coupling in a Mixed‐Valence Hexavanadate Core: Quantum‐Chemical Forecast" @default.
- W2053275320 cites W1577436442 @default.
- W2053275320 cites W1602639107 @default.
- W2053275320 cites W1972931532 @default.
- W2053275320 cites W1975153728 @default.
- W2053275320 cites W1984128403 @default.
- W2053275320 cites W1993107507 @default.
- W2053275320 cites W1995648328 @default.
- W2053275320 cites W1996048545 @default.
- W2053275320 cites W1999304304 @default.
- W2053275320 cites W2003251268 @default.
- W2053275320 cites W2007773813 @default.
- W2053275320 cites W2023271753 @default.
- W2053275320 cites W2026790525 @default.
- W2053275320 cites W2028902398 @default.
- W2053275320 cites W2037328368 @default.
- W2053275320 cites W2041041109 @default.
- W2053275320 cites W2042424392 @default.
- W2053275320 cites W2044814053 @default.
- W2053275320 cites W2045952721 @default.
- W2053275320 cites W2056385916 @default.
- W2053275320 cites W2058210956 @default.
- W2053275320 cites W2060526159 @default.
- W2053275320 cites W2062745494 @default.
- W2053275320 cites W2065415578 @default.
- W2053275320 cites W2066223077 @default.
- W2053275320 cites W2073956744 @default.
- W2053275320 cites W2074211668 @default.
- W2053275320 cites W2078146328 @default.
- W2053275320 cites W2086957099 @default.
- W2053275320 cites W2090155847 @default.
- W2053275320 cites W2094913641 @default.
- W2053275320 cites W2100085509 @default.
- W2053275320 cites W2101253601 @default.
- W2053275320 cites W2115254022 @default.
- W2053275320 cites W2132168234 @default.
- W2053275320 cites W2137860046 @default.
- W2053275320 cites W2143981217 @default.
- W2053275320 cites W605170700 @default.
- W2053275320 doi "https://doi.org/10.1002/ejic.200700421" @default.
- W2053275320 hasPublicationYear "2007" @default.
- W2053275320 type Work @default.
- W2053275320 sameAs 2053275320 @default.
- W2053275320 citedByCount "24" @default.
- W2053275320 countsByYear W20532753202013 @default.
- W2053275320 countsByYear W20532753202014 @default.
- W2053275320 countsByYear W20532753202015 @default.
- W2053275320 countsByYear W20532753202016 @default.
- W2053275320 countsByYear W20532753202017 @default.
- W2053275320 countsByYear W20532753202018 @default.
- W2053275320 countsByYear W20532753202019 @default.
- W2053275320 crossrefType "journal-article" @default.
- W2053275320 hasAuthorship W2053275320A5020930375 @default.
- W2053275320 hasAuthorship W2053275320A5027554432 @default.
- W2053275320 hasAuthorship W2053275320A5028535289 @default.
- W2053275320 hasAuthorship W2053275320A5051502997 @default.
- W2053275320 hasAuthorship W2053275320A5067485436 @default.
- W2053275320 hasConcept C121332964 @default.
- W2053275320 hasConcept C123669783 @default.
- W2053275320 hasConcept C147120987 @default.
- W2053275320 hasConcept C147597530 @default.
- W2053275320 hasConcept C147789679 @default.
- W2053275320 hasConcept C159467904 @default.
- W2053275320 hasConcept C168900304 @default.
- W2053275320 hasConcept C178790620 @default.
- W2053275320 hasConcept C179104552 @default.
- W2053275320 hasConcept C184779094 @default.
- W2053275320 hasConcept C185592680 @default.
- W2053275320 hasConcept C186927785 @default.
- W2053275320 hasConcept C26873012 @default.
- W2053275320 hasConcept C2991951333 @default.
- W2053275320 hasConcept C32909587 @default.
- W2053275320 hasConcept C36678784 @default.
- W2053275320 hasConcept C38649801 @default.
- W2053275320 hasConcept C504678139 @default.
- W2053275320 hasConcept C62520636 @default.
- W2053275320 hasConcept C69523127 @default.
- W2053275320 hasConcept C71240020 @default.
- W2053275320 hasConcept C75079739 @default.
- W2053275320 hasConcept C82217956 @default.
- W2053275320 hasConcept C86025842 @default.
- W2053275320 hasConceptScore W2053275320C121332964 @default.
- W2053275320 hasConceptScore W2053275320C123669783 @default.
- W2053275320 hasConceptScore W2053275320C147120987 @default.
- W2053275320 hasConceptScore W2053275320C147597530 @default.
- W2053275320 hasConceptScore W2053275320C147789679 @default.
- W2053275320 hasConceptScore W2053275320C159467904 @default.
- W2053275320 hasConceptScore W2053275320C168900304 @default.
- W2053275320 hasConceptScore W2053275320C178790620 @default.