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- W2053277822 abstract "The reaction of iPr2InCl (1) with KF and 15-crown-5 in acetonitrile at room temperature leads to the toluene-soluble crown ether salt [K(15-crown-5)2][iPr2InCl2] (2) and to the MeCN-soluble diorganoindium fluoride iPr2InF (3). Pure 3 can be isolated, when the reaction is carried out with KF but without crown ether at −15°C. Crystals of 1 und 2, suitable for X-ray structure determinations, were obtained when 1 and 2 were recrystallized from toluene. 1 exists as infinite chains of the monomeric unit iPr2InCl, while the unit cell of 2 contains separate ions. Die Reaktion von iPr2InCl (1) mit KF und 15-Krone-5 in Acetonitril bei Raumtemperatur liefert das in Toluol lösliche Kronenethersalz [K(I5-Krone-5)2][iPr2InCl2] (2) und das in MeCN lösliche Diorganoindiumfluorid iPr2InF (3). Reines 3 kann erhalten werden, wenn die Umsetzung ohne Kronenether mit KF bei −15°C durchgeführt wird. Für eine Röntgenstrukturanalyse geeignete Kristalle von 1 und 2 können durch Umkristallisieren aus Toluol isoliert werden. 1 besteht dabei aus unendlichen Ketten der monomeren Einheit iPr2InCl, während die Elementarzelle von 2 isolierte Ionen enthält." @default.
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- W2053277822 date "1992-11-01" @default.
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- W2053277822 title "Synthese und Charakterisierung von iPr2InF und [K(15-Krone-5)2][IPr2InCl2]. Die Kristallstrukturen von [iPr2InCl] ∞ und [K(15-Krone-5)2][iPr2InCl2] Bernhard Neumüller" @default.
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- W2053277822 doi "https://doi.org/10.1016/0022-328x(92)80205-c" @default.
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