Matches in SemOpenAlex for { <https://semopenalex.org/work/W2053282654> ?p ?o ?g. }
Showing items 1 to 62 of
62
with 100 items per page.
- W2053282654 abstract "Abstract The interesting F 5 SCC-System is known, but its reactions are only partially investigated. Here we describe cyclisation reactions. Thermal excitation up to 360°C does not show any results. HCCSF 5 trimerises under uv irradiation (λ = 254 nm) under formation of 1,3,5- trispentafluorothiobenzene. F 5 SCCSF 5 does not trimerise, however, under such conditions. Co 2 (CO) 8 incorporates HCCSF 5 , giving Co 2 (CO) 6 (HCCSF 5 ) as intermediate and Co 2 (CO) 4 (HCCSF 5 ) 3 as final product. The latter has been structurally investigated by x-ray. The three acetylene functions in the complex are linked together in such a manner, that under decomposition 1,2,4-trispentafluorothiobenzene must result. F 5 SCCSF 5 and (CH 3 ) 3 SiCCSF 5 react only to Co 2 (CO) 6 (F 5 SCCSF 5 ) and Co 2 (CO) 6 [(CH 3 ) 3 SiCCSF 5 ], respectively. The halogenated acetylenes XCCSF 5 (X = Cl, Br, I) have been prepared also and are surprisingly stable." @default.
- W2053282654 created "2016-06-24" @default.
- W2053282654 creator A5012947921 @default.
- W2053282654 creator A5018297709 @default.
- W2053282654 date "1985-08-01" @default.
- W2053282654 modified "2023-09-27" @default.
- W2053282654 title "Some reactions of F5SCCH and F5SCCSF5" @default.
- W2053282654 doi "https://doi.org/10.1016/s0022-1139(00)83326-6" @default.
- W2053282654 hasPublicationYear "1985" @default.
- W2053282654 type Work @default.
- W2053282654 sameAs 2053282654 @default.
- W2053282654 citedByCount "0" @default.
- W2053282654 crossrefType "journal-article" @default.
- W2053282654 hasAuthorship W2053282654A5012947921 @default.
- W2053282654 hasAuthorship W2053282654A5018297709 @default.
- W2053282654 hasConcept C111337013 @default.
- W2053282654 hasConcept C121332964 @default.
- W2053282654 hasConcept C124681953 @default.
- W2053282654 hasConcept C155647269 @default.
- W2053282654 hasConcept C160434732 @default.
- W2053282654 hasConcept C178790620 @default.
- W2053282654 hasConcept C185544564 @default.
- W2053282654 hasConcept C185592680 @default.
- W2053282654 hasConcept C2777517455 @default.
- W2053282654 hasConcept C71240020 @default.
- W2053282654 hasConceptScore W2053282654C111337013 @default.
- W2053282654 hasConceptScore W2053282654C121332964 @default.
- W2053282654 hasConceptScore W2053282654C124681953 @default.
- W2053282654 hasConceptScore W2053282654C155647269 @default.
- W2053282654 hasConceptScore W2053282654C160434732 @default.
- W2053282654 hasConceptScore W2053282654C178790620 @default.
- W2053282654 hasConceptScore W2053282654C185544564 @default.
- W2053282654 hasConceptScore W2053282654C185592680 @default.
- W2053282654 hasConceptScore W2053282654C2777517455 @default.
- W2053282654 hasConceptScore W2053282654C71240020 @default.
- W2053282654 hasLocation W20532826541 @default.
- W2053282654 hasOpenAccess W2053282654 @default.
- W2053282654 hasPrimaryLocation W20532826541 @default.
- W2053282654 hasRelatedWork W1783605802 @default.
- W2053282654 hasRelatedWork W1984971667 @default.
- W2053282654 hasRelatedWork W1985328138 @default.
- W2053282654 hasRelatedWork W2017825142 @default.
- W2053282654 hasRelatedWork W2020794662 @default.
- W2053282654 hasRelatedWork W2040083143 @default.
- W2053282654 hasRelatedWork W2041634530 @default.
- W2053282654 hasRelatedWork W2048147595 @default.
- W2053282654 hasRelatedWork W2059572389 @default.
- W2053282654 hasRelatedWork W2061377775 @default.
- W2053282654 hasRelatedWork W2062046216 @default.
- W2053282654 hasRelatedWork W2083770213 @default.
- W2053282654 hasRelatedWork W2094167458 @default.
- W2053282654 hasRelatedWork W2096908853 @default.
- W2053282654 hasRelatedWork W2140019902 @default.
- W2053282654 hasRelatedWork W2142418080 @default.
- W2053282654 hasRelatedWork W2143148651 @default.
- W2053282654 hasRelatedWork W3005750118 @default.
- W2053282654 hasRelatedWork W82139459 @default.
- W2053282654 hasRelatedWork W1969414592 @default.
- W2053282654 isParatext "false" @default.
- W2053282654 isRetracted "false" @default.
- W2053282654 magId "2053282654" @default.
- W2053282654 workType "article" @default.